Patents and Intellectual Property

romMax technology is covered by a number of patent applications. In the late 1990s, Nalco applied for and received a patent for its version of stabilized bromine. The process is quite simple. Sodium bromide is oxidized with sodium hypochlorite (bleach) and subsequently stabilized using a nitrogen-sulfur based organic acid, which is the typical stabilizer for all stabilized bromine formulations and processes. The active bromine (reported as active Cl) is 6.0%. The process has several major drawbacks.

Due to the alkaline conditions created by mixing bleach and sodium bromide, a considerable amount of bromate ion is created, which is a suspected carcinogen and is tightly regulated by the EPA in drinking water, lakes, rivers, and water table aquifers. Secondly, its uppermost concentration is limited by the strength of the commercial bleach (12-15% as NaOCl) that is used to make the product. Furthermore, it is well known that bleach is an equimolar solution of NaOCl and NaCl. As a result, a large excess of inert NaCl (salt) is inadevertently added and co-produced in the reaction. Attempts to increase the strength of commercial quantities above about 6.0-6.1% active Cl are restricted due to this inert salt. (At higher concentrations it would precipitate NaCl salt and other inert by-products in the drum or container).

Also in the late 1990s the Albemarle Corporation was able to raise the bar on the upper limits of active stabilized bromine to about 6.8% (as active Cl). They use a process based on bromine chloride. Today's version probably is based on co-feeding bromine gas and chlorine gas into the process reactor, and subsequently stabilizing the product using the same nitrogen-sulfur based organic acid as mentioned above. The subsequent patents were issued to Albemarle on their process due to the fact that it was probably sufficiently different from processes disclosed by Nalco. Albemarle's product raised the physical stability characteristics of the finished product to allow a commercial product introduction that was about 12% more concentrated than Nalco's product. Still, the active Cl of Albemarle's product is limited to about 6.8% as Cl, again due to salt and inert by-product precipitation.

In 2002 Enviro Tech discovered a completely new way to make stabilized bromine. The process created almost 40% fewer salts and inert by-products that plague all manufacturers of stabilized bromine products. The end-product is almost identical to Nalco's and Albemarle's, with the exception that we are able to stabilize the bromine at 10.2% (as Cl). This equates to 67% and 48% more active bromine than Nalco or Albemarle, respectively.

Enviro Tech's process is quite ingenious. Sodium bromide is oxidized by a solid known as trichlor (trichloroisocyanuric acid), which is 91% available chlorine. The trick was to utilize the trichlor and extract its chlorine in a liquid process. Considering trichlor is only very marginally soluble in water makes the process that much more unique. Because trichlor is solid, no extraneous water is introduced to dilute the product as is the case when using 12-15% NaOCl bleach. Also, trichlor contains no solubility-limiting inert NaCl salts. The by-product of the Enviro Tech process is cyanuric acid and/or sodium cyanurate, which is insoluble and completely filtered out of solution. It is then washed and sold back to the chlorinated iso manufacturers to make more trichlor. Nothing is wasted, and the end-product is chemically and functionally the same as the two other products on the market…with the exception that BromMax is the best value for the dollar and is the most cost-competitive.

Our first patent application was published by the US-PTO in December 2004, and is available on the link below for your convenience. Enviro Tech has two more patents applications on this subject matter that have yet to be published or publicly disclosed. We will add them to the list as they become posted on the U.S. Patent and Trademark Office web site. The next one is due to be published in November 2005. It is designed to "fill the gaps" to prevent our competitors from utilizing our processes and inventions to improve their own products or intellectual property libraries. Enviro Tech's intellectual property for stabilized bromine has been filed in almost every progressive country in the world, so no matter where you may go, BromMax will be available.

Click on the link below to learn more. But beware: this is a large document (2.85 MB), and it may take a few moments to download. (Note that when clicking on the document listed below, it will open up in a separate window which may fill your browser. Once you close this window, you will be back on the Stabilized Bromine web site):

BromMax Patent #1 Issued 5-16-06 (2.75MB)

2nd Bromine UA20050249825A1 (1.7MB)

RECENT NEWS
Date
Milestone
July 2005
Enviro Tech was notified by the US Patent and Trademark Office, in the official "first office action," that our first patent was reviewed carefully and was determined to be distinctly different from all prior art, that our patent application would proceed unchanged, and that all claims associated with our application were acceptable without further comments or actions. Thus, our patent will probably be issued around the end of 2005.

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